Search
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
dibenzo[a,d]tropylium ion  |
dichloromethane | E Param.: -0.63 |  | Liebigs Ann. 1995, , 2005-2009 10.1002/jlac.1995199[...] |
(fur)2CH+ |
E Param.: -1.36 |  | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
(ani)2CH+ |
E Param.: 0.00 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
(tol)2CH+ |
E Param.: 3.63 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
(pfa)2CH+ |
E Param.: -3.14 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
(mfa)2CH+ |
E Param.: -3.85 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
(dpa)2CH+ |
E Param.: -4.72 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
(mor)2CH+ |
E Param.: -5.53 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
(mpa)2CH+ |
E Param.: -5.89 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
(dma)2CH+ |
E Param.: -7.02 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
(pyr)2CH+ |
E Param.: -7.69 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
(thq)2CH+ |
E Param.: -8.22 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
(ind)2CH+ |
E Param.: -8.76 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
(jul)2CH+ |
E Param.: -9.45 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
(lil)2CH+ |
E Param.: -10.04 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
m-xylene |
dichloromethane | N Param.: -3.57 sN Param.: 2.08 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
styrene |
dichloromethane | N Param.: 0.78 sN Param.: 0.95 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
1,3-dimethoxybenzene |
dichloromethane | N Param.: 2.48 sN Param.: 1.09 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
allyltriphenylstannane |
dichloromethane | N Param.: 3.09 sN Param.: 0.90 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
(2-methylallyl)trimethylsilane |
dichloromethane | N Param.: 4.41 sN Param.: 0.96 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
allyltributylstannane |
dichloromethane | N Param.: 5.46 sN Param.: 0.89 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
(2-methylallyl)tributylstannane |
dichloromethane | N Param.: 7.48 sN Param.: 0.89 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
Danishefskys diene |
dichloromethane | N Param.: 8.57 sN Param.: 0.84 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
2-(trimethylsiloxy)-5,6-dihydro-4H-pyran |
dichloromethane | N Param.: 10.61 sN Param.: 0.86 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
5-(trimethylsiloxy)-2,3-dihydrofuran |
dichloromethane | N Param.: 12.56 sN Param.: 0.70 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
methylenecyclopentane |
dichloromethane | N Param.: 2.82 sN Param.: 0.90 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
2-methylfuran |
dichloromethane | N Param.: 3.61 sN Param.: 1.11 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
N-methylpyrrole |
dichloromethane | N Param.: 5.85 sN Param.: 1.03 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
1-(trimethylsiloxy)cyclohexene |
dichloromethane | N Param.: 5.21 sN Param.: 1.00 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
2-(trimethylsiloxy)propene |
dichloromethane | N Param.: 5.41 sN Param.: 0.91 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
1-phenyl-1-(trimethylsiloxy)ethene |
dichloromethane | N Param.: 6.22 sN Param.: 0.96 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
1-(trimethylsiloxy)cyclopentene |
dichloromethane | N Param.: 6.57 sN Param.: 0.93 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
1-phenoxy-1-(trimethylsiloxy)ethene |
dichloromethane | N Param.: 8.23 sN Param.: 0.81 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
1-(N-morpholino)cyclohexene |
dichloromethane | N Param.: 11.40 sN Param.: 0.83 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
1-(N-piperidino)cyclohexene |
dichloromethane | N Param.: 13.36 sN Param.: 0.81 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
(Z)-but-2-ene |
dichloromethane | N Param.: -2.44 sN Param.: 1.09 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
allyltriphenylsilane |
dichloromethane | N Param.: -0.13 sN Param.: 1.21 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
3-methylanisole |
dichloromethane | N Param.: 0.13 sN Param.: 1.27 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
(triisopropylsiloxy)ethene |
dichloromethane | N Param.: 3.44 sN Param.: 0.94 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
(2-methylallyl)triphenylsilane |
dichloromethane | N Param.: 4.17 sN Param.: 0.79 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
2-(triisopropylsiloxy)propene |
dichloromethane | N Param.: 5.38 sN Param.: 0.85 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
triphenylgermane |
dichloromethane | N Param.: 3.99 sN Param.: 0.62 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
triphenylstannane |
dichloromethane | N Param.: 5.64 sN Param.: 0.59 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
tributylgermane |
dichloromethane | N Param.: 5.92 sN Param.: 0.73 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
borane-triethylamine-complex |
dichloromethane | N Param.: 8.90 sN Param.: 0.75 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
tributylstannane |
dichloromethane | N Param.: 9.96 sN Param.: 0.55 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
2-(bis(trimethylsiloxy)amino)propene |
dichloromethane | N Param.: 4.76 sN Param.: 0.86 | | J. Org. Chem. 2001, 66, 3196-3200 10.1021/jo0015927 |
(bis(trimethylsiloxy)amino)styrene |
dichloromethane | N Param.: 4.80 sN Param.: 0.86 | | J. Org. Chem. 2001, 66, 3196-3200 10.1021/jo0015927 |
2-(bis(tert-butyldimethylsiloxy)amino)propene |
dichloromethane | N Param.: 4.23 sN Param.: 0.93 | | J. Org. Chem. 2001, 66, 3196-3200 10.1021/jo0015927 |
4-(bis(trimethylsiloxy)amino)pent-4-enoic acid methyl ester |
dichloromethane | N Param.: 3.84 sN Param.: 0.87 | | J. Org. Chem. 2001, 66, 3196-3200 10.1021/jo0015927 |
1-methylcyclohexene |
dichloromethane | N Param.: 0.08 sN Param.: 1.15 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
2-methyl-but-2-ene |
dichloromethane | N Param.: 0.65 sN Param.: 1.17 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
2-methylpropene (isobutylene) |
dichloromethane | N Param.: 1.11 sN Param.: 0.98 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
1-methyl-4-vinyl-benzene |
dichloromethane | N Param.: 1.70 sN Param.: 1.06 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
2-methyl-buta-1,3-diene (isoprene) |
dichloromethane | N Param.: 1.10 sN Param.: 0.98 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
trimethyl(prenyl)silane |
dichloromethane | N Param.: 0.90 sN Param.: 1.17 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
(2-methylallyl)triphenylgermane |
dichloromethane | N Param.: 4.67 sN Param.: 0.81 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
1-ethinylcyclohexenyl-Co2(CO)6 |
dichloromethane | N Param.: -0.44 sN Param.: 1.06 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
4-(trimethylsilyl)but-1-en-3-ynyl-Co2(CO)6 |
dichloromethane | N Param.: -1.11 sN Param.: 0.92 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
cyclohepta-1,3,5-trienyl-Fe(CO)3 |
dichloromethane | N Param.: 3.42 sN Param.: 0.94 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
ani(pop)CH+ |
E Param.: 0.61 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
ani(Ph)CH+ |
E Param.: 2.11 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
ani(tol)CH+ |
E Param.: 1.48 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
pop(Ph)CH+ |
E Param.: 2.90 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
fc(Ph)CH+ |
E Param.: -2.64 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
3,3-dimethyl-2-(trimethylsiloxy)buten |
dichloromethane | N Param.: 3.78 sN Param.: 0.79 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
1-methoxy-2-methyl-1-(trimethylsiloxy)propene |
dichloromethane | N Param.: 9.00 sN Param.: 0.98 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
2-methyl-1-(trimethylsiloxy)propen |
dichloromethane | N Param.: 3.94 sN Param.: 1.00 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
ani(Br)2QM |
E Param.: -8.63 | | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] | |
ani(Ph)2QM |
E Param.: -12.18 | | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] | |
dma(Ph)2QM |
E Param.: -13.39 | | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] | |
tol(t-Bu)2QM |
E Param.: -15.83 | | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] | |
ani(t-Bu)2QM |
E Param.: -16.11 | | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] | |
dma(t-Bu)2QM |
E Param.: -17.29 | | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] | |
jul(t-Bu)2QM |
E Param.: -17.90 | | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] | |
cycloheptatriene |
dichloromethane | N Param.: 0.52 sN Param.: 0.97 | | J. Am. Chem. Soc. 2002, 124, 4076-4083 10.1021/ja0121538 |
N-vinylcarbazole |
dichloromethane | N Param.: 5.02 sN Param.: 0.94 | | Macromolecules 2002, 35, 5454-5458 10.1021/ma020306l |
1,4-cyclohexadiene |
dichloromethane | N Param.: 0.09 sN Param.: 0.98 | | J. Am. Chem. Soc. 2002, 124, 4076-4083 10.1021/ja0121538 |
1,4-dihydronaphthalene |
dichloromethane | N Param.: -0.07 sN Param.: 1.03 | | J. Am. Chem. Soc. 2002, 124, 4076-4083 10.1021/ja0121538 |
9,10-dihydroanthracene |
dichloromethane | N Param.: -0.86 sN Param.: 0.92 | | J. Am. Chem. Soc. 2002, 124, 4076-4083 10.1021/ja0121538 |
(E,E)-2,5-heptadiene |
dichloromethane | N Param.: -0.74 sN Param.: 0.99 | | J. Am. Chem. Soc. 2002, 124, 4076-4083 10.1021/ja0121538 |
3-propylcyclopentene |
dichloromethane | N Param.: -0.88 sN Param.: 0.94 | | J. Am. Chem. Soc. 2002, 124, 4076-4083 10.1021/ja0121538 |
xanthene |
dichloromethane | N Param.: 0.64 sN Param.: 0.97 | | J. Am. Chem. Soc. 2002, 124, 4076-4083 10.1021/ja0121538 |
4-methyl-2,5-heptadiene |
dichloromethane | N Param.: -0.73 sN Param.: 0.97 | | J. Am. Chem. Soc. 2002, 124, 4076-4083 10.1021/ja0121538 |
3-methyl-1,4-pentadiene |
dichloromethane | N Param.: -3.08 sN Param.: 0.97 | | J. Am. Chem. Soc. 2002, 124, 4076-4083 10.1021/ja0121538 |
1,4-pentadiene |
dichloromethane | N Param.: -2.99 sN Param.: 0.97 | | J. Am. Chem. Soc. 2002, 124, 4076-4083 10.1021/ja0121538 |
p-cymene |
dichloromethane | N Param.: -2.80 sN Param.: 0.97 | | J. Am. Chem. Soc. 2002, 124, 4076-4083 10.1021/ja0121538 |
allylbenzene |
dichloromethane | N Param.: -4.12 sN Param.: 0.97 | | J. Am. Chem. Soc. 2002, 124, 4076-4083 10.1021/ja0121538 |
anion of Meldrums acid (in DMSO) |
DMSO | N Param.: 13.91 sN Param.: 0.86 | | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
anion of dimedone (in DMSO) |
DMSO | N Param.: 16.27 sN Param.: 0.77 | | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
anion of acetylacetone (in DMSO) |
DMSO | N Param.: 17.64 sN Param.: 0.73 | | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
anion of ethyl acetylacetate (in DMSO) |
DMSO | N Param.: 18.82 sN Param.: 0.69 | | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
anion of malononitrile (in DMSO) |
DMSO | N Param.: 19.36 sN Param.: 0.67 | | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
anion of ethyl cyanoacetate (in DMSO) |
DMSO | N Param.: 19.62 sN Param.: 0.67 | | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
anion of diethyl malonate (in DMSO) |
DMSO | N Param.: 20.22 sN Param.: 0.65 | | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
5-methoxyfuroxano[3,4-d]pyrimidine |
E Param.: -8.37 | | J. Phys. Org. Chem. 2003, 16, 431-437 10.1002/poc.606 | |
1-(N-pyrrolidino)cyclopentene |
dichloromethane | N Param.: 15.91 sN Param.: 0.86 | | Chem. Eur. J. 2003, 9, 2209-2218 10.1002/chem.200204666 |
1-(N-piperidino)cyclopentene |
dichloromethane | N Param.: 15.06 sN Param.: 0.82 | | Chem. Eur. J. 2003, 9, 2209-2218 10.1002/chem.200204666 |
1-(N-pyrrolidino)cyclohexene |
dichloromethane | N Param.: 14.91 sN Param.: 0.86 | | Chem. Eur. J. 2003, 9, 2209-2218 10.1002/chem.200204666 |
1-(N-morpholino)cyclopentene |
dichloromethane | N Param.: 13.41 sN Param.: 0.82 | | Chem. Eur. J. 2003, 9, 2209-2218 10.1002/chem.200204666 |
News
- 11/05/25:
Isochalcogenoureas (O, S, Se & Te derivatives) have been added (Angew. Chem. Int. Ed. 2025, EarlyView, e202514865). - 01/30/25:
Sesamol-derived ortho-quinone methides (o-QM) have been added (ChemEurJ 2024, e202403785 & OBC 2025, 23, 827-834) - 05/22/24:
Lactone enolates have been added (JOC 2024, 89, 6915-6928). - 11/13/24:
2-Methylene-1,2-dihydropyridines (2-pyNHOs) have been added (EurJOC 2024, 27, e202400373). - 05/21/24:
Mesoionic pyridinium-derived N-heterocyclic olefins (py-mNHOs) have been added (Angew. Chem. Int. Ed. 2024, 63, e202318283). - 10/19/23:
Enamines derived from 4-(alkylthio)-3-imidazolines and aldehydes have been added (ChemEurJ 2023, doi: 10.1002/chem.202302764). - 09/28/23:
Mesoionic N-heterocyclic olefins (mNHOs) have been added (Angew. Chem. Int. Ed. 2023, 62, e202309790). - 07/05/23:
S-Cyanomethylated imidazolidine-4-thione-derived enamines have been added (ChemComm 2023, 59, 8091). - 03/16/23:
Cyclic alpha-diazo carbonyl compounds added (EurJOC 2023, 26, e202300005) - 01/30/23:
NADH and NADPH reactivities (in water, pH 7) determined by Mayer and Moran have been added (OBC 2022, 21, 85-88). - 09/20/22:
Alkenyl boronate nucleophilicity by Liu, Ready and co-workers has been added (JACS 2022, 144, 16118). - 01/30/23:
Electrophilicities of diazo compounds in azo couplings (ChemEurJ 2022, 28, e202201376) - 01/30/23:
Diazocyclopentadiene added (Synthesis 2023, 55, 354-358) - 01/30/23:
Electrophilic indoles added (ChemCommun 2021, 57, 10071-10074) - 04/13/21:
Cyclic Michael acceptors added (Chem. Sci. 2021, 12, 4850-4865) - 05/21/21:
Thiophenolates (in DMSO) added (JOC 2021, 86, 5965-5972) - 05/06/20:
Heteroallenes added (JACS 2020, 142, 8383-8402). - 01/27/20:
Pyrrolidines and Imidazolidinones added (JACS 2020, 142, 1526-1547). - 05/06/20:
GSH reactivity added (Angew. Chem. Int. Ed. 2019, 58, 17704-17708) - 01/30/23:
Phenolates added (JOC 2019, 84, 8837-8858) - 04/24/18:
Ketones added (JACS 2018, 140, 5500). - 11/03/17:
Allyl-boron nucleophiles added (JACS 2017, 139, 15324) - 04/23/18:
Peroxide anions added (Angew. Chem. Int. Ed. 2017, 56, 13279). - 04/23/18:
Michael acceptors added (JACS 2017, 139, 13318). - 06/16/17:
Nucleophilicities of VNS reagents (JOC 2017, 82, 1011).