Mayr's Database of Reactivity Parameters

2-trimethylsiloxy-buta-1,3-diene

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Enol Ethers » C=C-OSi

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Name 2-trimethylsiloxy-buta-1,3-diene
Structure
image of molecule
Molecule class Nucleophiles » C-Nucleophiles » Enol Ethers » C=C-OSi
SMILES C=C(C=C)O[Si](C)(C)C
Molecular formula C7H14OSi
Quality ***
Parameters

N  Param.: 4.93

sN Param.: 0.95
Comment

A previously published N = 4.83 [Acc. Chem. Res. 2003] was determined with only one reference electrophile (sN = 0.90 was estimated) and has been revised in Org. Chem. Front. 2026 after inclusion of additional kinetic data.

 
Solvent dichloromethane
Reference Org. Chem. Front. 2026, AdvArticle,
10.1039/d6qo01106c