Mayr's Database of Reactivity Parameters

Carbocations

For reactivities of structurally related compounds go to: Electrophiles » C-Electrophiles » Carbocations

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
(dfp)2CH+
C13H7F4 *

E Param.: 8.02

 * J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
(tfm)2CH+
C15H9F6 *

E Param.: 7.96

 ** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
(dfp)(mfp)CH+
C13H8F3 *

E Param.: 7.52

 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
(mfp)2CH+
C13H9F2 *

E Param.: 6.87

 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
(dfp)PhCH+
C13H9F2 *

E Param.: 6.74

 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
(tfm)PhCH+
C14H10F3 *

E Param.: 6.70

 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
(mfp)PhCH+
C13H10F *

E Param.: 6.23

 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
1,3-bis(2,4,6-trimethylphenyl)but-1-ylium ion
C22H29 *

E Param.: 6.16

 * Macromolecules 2005, 38, 33-40
10.1021/ma048389o
diarylallylium ion (3,3-F2)2
*

E Param.: 6.11

 *** J. Org. Chem. 2011, 76, 9391-9408
10.1021/jo201668w
(2,4,6-trimethylphenyl)ethylium ion
C11H15 *

E Param.: 6.04

 * Macromolecules 2005, 38, 33-40
10.1021/ma048389o