Mayr's Database of Reactivity Parameters

Carbocations

For reactivities of structurally related compounds go to: Electrophiles » C-Electrophiles » Carbocations

6 | 7 | 8 | 9 | 10 | 11 | 12 | 13 | 14 | « Back Forward » Found 134 molecules, showing page 12 of 14
Results per page: 10 | 50 | 100 | all
Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
Jorgensen/Hayashi-iminium ion
C29H34NOSi+ *

E Param.: -8.20

 *** Angew. Chem. Int. Ed. 2008, 47, 8723-8726
10.1002/anie.200802889
(thq)2CH+
C21H25N2 *

E Param.: -8.22

 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
p-CF3-C6H4-CH=N+Me2 (in MeCN)
C10H11F3N *
 MeCN

E Param.: -8.34

 *** J. Am. Chem. Soc. 2013, 135, 6579-6587
10.1021/ja401106x
(PhCH2)2N+=CH-CH-Ph
C23H22N+ *

E Param.: -8.50

 *** Angew. Chem. Int. Ed. 2008, 47, 8723-8726
10.1002/anie.200802889
mor iminium
C13H16NO+ *

E Param.: -8.60

 *** Angew. Chem. Int. Ed. 2008, 47, 8723-8726
10.1002/anie.200802889
(ind)2CH+
C19H21N2 *

E Param.: -8.76

 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
1,1-bis(4-dimethylaminophenyl)-3-phenylallylium ion
*

E Param.: -8.97, Deviation: ±0.32

 *** Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
Me2N+=CH-CH-Ph
C11H14N+ *

E Param.: -9.20

 *** Angew. Chem. Int. Ed. 2008, 47, 8723-8726
10.1002/anie.200802889
PhCH=N+Me2 (in MeCN)
C9H12N *
 MeCN

E Param.: -9.27

 *** J. Am. Chem. Soc. 2013, 135, 6579-6587
10.1021/ja401106x
PhCH=N+(CH2)4 (in MeCN)
C11H14N *
 MeCN

E Param.: -9.35

 *** J. Am. Chem. Soc. 2013, 135, 6579-6587
10.1021/ja401106x