Mayr's Database of Reactivity Parameters

N-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles » N-Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
4-(dimethylamino)pyridine (in 91M9AN)
C7H10N2 *
 MeOH-MeCN mix

N  Param.: 13.20

sN Param.: 0.67		 * Chem. Eur. J. 2007, 13, 336-345
10.1002/chem.200600941
4-(dimethylamino)pyridine (in CH2Cl2)
C7H10N2 *
 dichloromethane

N  Param.: 15.80

sN Param.: 0.66		 *** Chem. Eur. J. 2007, 13, 336-345
10.1002/chem.200600941
4-(dimethylamino)pyridine (in DMF)
C7H10N2 *
 DMF

N  Param.: 14.90

sN Param.: 0.67		 * Chem. Eur. J. 2007, 13, 336-345
10.1002/chem.200600941
4-(dimethylamino)pyridine (in DMSO)
C7H10N2 *
 DMSO

N  Param.: 14.80

sN Param.: 0.67		 * Chem. Eur. J. 2007, 13, 336-345
10.1002/chem.200600941
4-(dimethylamino)pyridine (in H2O)
C7H10N2 *
 water

N  Param.: 13.19

sN Param.: 0.56		 *** Chem. Eur. J. 2007, 13, 336-345
10.1002/chem.200600941
4-(dimethylamino)pyridine (in MeCN)
C7H10N2 *
 MeCN

N  Param.: 15.51

sN Param.: 0.62		 *** J. Phys. Chem. A 2012, 116, 8494-8499
10.1021/jp3049247
4-(dimethylamino)pyridine (in THF)
*
 THF

N  Param.: 15.90

sN Param.: 0.66		 *** Angew. Chem. Int. Ed. 2011, 50, 6915-6919
10.1002/anie.201102435
4-(morpholino)pyridine (in CH2Cl2)
C9H12N2O *
 dichloromethane

N  Param.: 14.59

sN Param.: 0.69		 *** Eur. J. Org. Chem. 2016, , 4050-4058
10.1002/ejoc.201600572
4-(morpholino)pyridine (in MeCN)
*
 MeCN

N  Param.: 14.80

sN Param.: 0.63		 *** J. Phys. Chem. A 2012, 116, 8494-8499
10.1021/jp3049247
4-acetamido-pyridine (in MeCN)
*
 MeCN

N  Param.: 13.24

sN Param.: 0.67		 *** J. Phys. Chem. A 2012, 116, 8494-8499
10.1021/jp3049247