Mayr's Database of Reactivity Parameters

Alkenes

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Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
(E)-propenylbenzene
C9H10 *
dichloromethane

N  Param.: -0.49

sN Param.: 1.18
***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
methylenecyclopropane
C4H6 *
dichloromethane

N  Param.: -0.47

sN Param.: 0.90
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
norbornene
C7H10 *
dichloromethane

N  Param.: -0.25

sN Param.: 1.09
***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
2,3,3-trimethyl-but-1-ene
C7H14 *
dichloromethane

N  Param.: 0.06

sN Param.: 1.07
***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
cyclohepta-1,3-diene
C7H10 *
dichloromethane

N  Param.: 0.06

sN Param.: 1.10
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
1-methylcyclohexene
C7H12 *
dichloromethane

N  Param.: 0.08

sN Param.: 1.15
***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
(2-methylallyl)benzene
C10H12 *
dichloromethane

N  Param.: 0.25

sN Param.: 1.00
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
2,4-dimethyl-penta-1,4-diene
C7H12 *
dichloromethane

N  Param.: 0.54

sN Param.: 1.00
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
2-methyl-but-2-ene
C5H10 *
dichloromethane

N  Param.: 0.65

sN Param.: 1.17
***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
2,3-dimethyl-but-1-ene
C6H12 *
dichloromethane

N  Param.: 0.65

sN Param.: 1.00
***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b