Mayr's Database of Reactivity Parameters

H-C hydride donors

For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles » H-C hydride donors

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
1,4-pentadiene
C5H8 *
 dichloromethane

N  Param.: -2.99

sN Param.: 0.97		 * J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
p-cymene
C10H14 *
 dichloromethane

N  Param.: -2.80

sN Param.: 0.97		 * J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
allylbenzene
C9H10 *
 dichloromethane

N  Param.: -4.12

sN Param.: 0.97		 * J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
cycloheptatriene (in MeCN)
C7H8 *
 MeCN

N  Param.: 0.55

sN Param.: 0.97		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,4-cyclohexadiene (in MeCN)
*
 MeCN

N  Param.: 0.35

sN Param.: 0.98		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-phenyldioxolane
C9H10O2 *
 dichloromethane

N  Param.: -0.90

sN Param.: 0.80		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
N-benzyl-1,4-dihydronicotineamide (in MeCN)
*
 MeCN

N  Param.: 9.80

sN Param.: 0.70		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
N-benzyl-1,4-dihydronicotineamide (in 50W50AN)
*
 water-MeCN mix

N  Param.: 9.79

sN Param.: 0.70		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
N-benzyl-1,4-dihydronicotineamide (in 67W33AN)
*
 water-MeCN mix

N  Param.: 10.19

sN Param.: 0.70		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
N-benzyl-1,4-dihydronicotineamide (in 80W20AN)
*
 water-MeCN mix

N  Param.: 10.67

sN Param.: 0.70		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839