Ylides
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
Ph3P=CH-COPh   |
dichloromethane | N Param.: 9.54 sN Param.: 0.97 |
 |
J. Am. Chem. Soc. 2009, 131, 704-714 10.1021/ja8056216 |
Ph3P=CH-CO2Et (in DMSO)  |
DMSO | N Param.: 12.21 sN Param.: 0.62 |
|
J. Am. Chem. Soc. 2009, 131, 704-714 10.1021/ja8056216 |
Ph3P=CH-CO2Et  |
dichloromethane | N Param.: 12.79 sN Param.: 0.77 |
|
J. Am. Chem. Soc. 2009, 131, 704-714 10.1021/ja8056216 |
Ph3P=CH-CN  |
dichloromethane | N Param.: 12.29 sN Param.: 0.75 |
|
J. Am. Chem. Soc. 2009, 131, 704-714 10.1021/ja8056216 |
Ph3P=CH-CHO (in MeCN)  |
MeCN | N Param.: 9.09 sN Param.: 0.74 |
|
J. Am. Chem. Soc. 2016, 138, 11272-11281 10.1021/jacs.6b06264 |
Ph3P=CH-C(O)Me (in MeCN)  |
MeCN | N Param.: 10.27 sN Param.: 0.83 |
|
J. Am. Chem. Soc. 2016, 138, 11272-11281 10.1021/jacs.6b06264 |
Ph3P=C(CH3)-CO2Et  |
dichloromethane | N Param.: 13.09 sN Param.: 0.73 |
|
J. Am. Chem. Soc. 2009, 131, 704-714 10.1021/ja8056216 |
N,N-Dimethylbarbituric acid iodonium ylide (in CHCl2)  |
dichloromethane | N Param.: 7.98 sN Param.: 0.71 |
|
J. Am. Chem. Soc. 2016, 138, 10304-10313 10.1021/jacs.6b05768 |
Meldrum's acid iodonium ylide (in CH2Cl2)  |
dichloromethane | N Param.: 4.36 sN Param.: 1.06 |
|
J. Am. Chem. Soc. 2016, 138, 10304-10313 10.1021/jacs.6b05768 |
Me2S=CH-CO2Et (in DMSO)  |
DMSO | N Param.: 15.85 sN Param.: 0.61 |
|
Chem. Eur. J. 2010, 16, 8610-8614 10.1002/chem.201001455 |