Warning (2): unserialize() [function.unserialize]: Extra data starting at offset 743 of 1498 bytes [CORE/cake/libs/cache/file.php, line 190]

                $data = str_replace('\\\\\\\\', '\\', $data);
            }
            $data = unserialize((string)$data);

unserialize - [internal], line ??
FileEngine::read() - CORE/cake/libs/cache/file.php, line 190
Cache::read() - CORE/cake/libs/cache.php, line 362
DataSource::__cacheDescription() - CORE/cake/libs/model/datasources/datasource.php, line 475
DataSource::describe() - CORE/cake/libs/model/datasources/datasource.php, line 278
DboMysqlBase::describe() - CORE/cake/libs/model/datasources/dbo/dbo_mysql.php, line 120
Model::schema() - CORE/cake/libs/model/model.php, line 938
Model::setSource() - CORE/cake/libs/model/model.php, line 789
Model::__construct() - CORE/cake/libs/model/model.php, line 483
ClassRegistry::init() - CORE/cake/libs/class_registry.php, line 142
Controller::loadModel() - CORE/cake/libs/controller/controller.php, line 634
Controller::constructClasses() - CORE/cake/libs/controller/controller.php, line 501
Dispatcher::_invoke() - CORE/cake/dispatcher.php, line 186
Dispatcher::dispatch() - CORE/cake/dispatcher.php, line 171
[main] - APP/webroot/index.php, line 83

Details of Molecule anion of diethyl methylmalonate (in water)

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Carbanions » Carbanions in water

go back to last page

Structure
Molecule class	Nucleophiles » C-Nucleophiles » Carbanions » Carbanions in water
Quality
Parameters	N Parameter: 17.68 s_N Parameter: 0.50
Comment	N and s_N were determined with (quasi) reference electrophiles (uncertain because pKa is not available!).
Sum formula	C8H13O4-
Solvent	water
Reference	J. Am. Chem. Soc. 2003, 125, 12980-12986 DOI: 10.1021/ja036838e