Shinya Minegishi
M. Eng., Dr.
Shinya preparing new compounds for his studies.
Reactivity Selectivity Relationships in Reactions of Carbocations with Nucleophiles
(finished 03/2004)
Electrophilic alkylations in neutral aqueous or alcoholic solutions
H. Mayr, M. Hofmann, S. Minegishi, N. Hampel, 2005, WO 2005077863.
Kinetics of the Reactions of Halide Anions with Carbocations: Quantitative Energy Profiles for SN1 Reactions
S. Minegishi, R. Loos, S. Kobayashi, H. Mayr, J. Am. Chem. Soc. 2005, 127, 2641-2649.
Solvent Nucleophilicity
S. Minegishi, S. Kobayashi, H. Mayr, J. Am. Chem. Soc. 2004, 126, 5174-5181.
SN1-Reaktionen mit inversen Geschwindigkeitsprofilen
SN1 Reactions with Inverse Rate Profiles
B. Denegri, S. Minegishi, O. Kronja, H. Mayr, Angew. Chem. 2004, 116, 2353-2356; Angew. Chem. Int. Ed. 2004, 43, 2302-2305.
How Constant are Ritchie’s "Constant Selectivity Relationships"? – A General Reactivity Scale for n-, p-, and s-Nucleophiles.
S. Minegishi, H. Mayr, J. Am. Chem. Soc. 2003, 125, 286-295.
Erstmalige direkte Beobachtung der beiden Einzelschritte einer SN1-Reaktion.
First Direct Observation of the Two Distinct Steps in an SN1 Reaction.
H. Mayr, S. Minegishi, Angew. Chem. 2002, 114, 4674-4676; Angew. Chem. Int. Ed. 2002, 41, 4493-4495.
Acid-Catalyzed Rearrangement of Ethynylcycloheptatriene to Phenylallene.
T. Kitagawa, J. Kamada, S. Minegishi, K. Takeuchi, Org. Lett. 2000, 2, 3011-3013.