-DEPARTMENT CHEMIE -  PHYSIKALISCHE CHEMIE - -
Ludwig-Maximilians -Universität München
AK Knözinger






1.

 

Patents:

H. Knözinger, J. Spengler, U. Schubert, R.-K. Grasselli, H.-J. Eberle
Offenlegungsschrift DE 197 17 344 A 1, 1998.
Verfahren zur Herstellung von Katalysatoren für die selektive Oxidation von aromatischen Kohlenwasserstoffen.

2.

T. Scherg, H. Meixner, H. Knözinger, B. Leyer
Offenlegungsschrift DE 197 13 148.4, 1998.
Verfahren zur Synthese von Aluminiumvanadat und Darstellung einer gassensitiven Schicht.

3.

G. Meyer, E. Schwab, H. Landes, H. Knözinger
Offenlegungsschrift DE 198 54 635, 1998.
Trägerkatalysator und dessen Einsatz in der Hydrierung.

   
   

 

 

 

Publications of Prof. Dr. H. Knözinger since 1994    

Earlier publications

 

413

P. Ratnasamy, D. Srinivas, H. Knözinger
Adv. Catal. 48 (2004) 1 - 169
Active Sites and Reactive Intermediates in Titanium Silicalite Molecular Sieves.

412

X. Carrier, P. Lukinskas, S. Kuba, L. Stievano, F. E. Wagner, M. Che, H. Knözinger
Chem. Phys. Chem., 5 (2004) 1191 - 1199
The State of Iron Promoters in Tungstated Zirconia Catalysts.

411

S. Günther, F. Esch, L. Gregoratti, A. Barinov, M. Kiskinova, E. Taglauer, H. Knözinger
J. Phys. Chem. B, 108 (2004) 14223 - 14231
Gas-Phase Transport during the Spreading of MoO3 an Al2O3 Support Surfaces: Photoelectron Spectromicroscopic Study.

410

K.Chakarova, E. Ivanova, K. Hadjiivanov, D. Klissurski, H. Knözinger
Phys. Chem. Chem. Phys., 5 (2004) 3702 - 3709
Co-ordination chemistry of palladium cations in Pd-H-ZSM-5 as revealed by FTIR spectra of adsorbed and co-adsorbed probe molecules (CO and NO).

409

M. Mihaylov, A. Penkova, K. Hadjiivanov, H. Knözinger
J. Phys. Chem. B, 108 (2004) 679 - 688
Formation of Surface Carbonyl and Nitrosyl Complexes on Titania - and Zirconia - supported Chromia.

408

S. Kannan, Tz.Venkov, K. Hadjiivanov, H. Knözinger
Langmuir, 20 (2004) 730 - 736
FTIR Study of Low-temperature CO Adsorption on CuMgAl-hydrotalcites

407

S. Kannan, V. Rives, H. Knözinger
J.Solid State Chem., 177 (2004) 319 - 331
High temperature transformations of Cu-rich hydrotalcites

406

A. Ponchel, F. Anderle, W. Daniell, H. Knözinger
Res. Chem. Intermed., 29 (2003) 705 - 719
Influence of phosphate modification on the surface properties of sulfated titania.

405

P. Vijayanand, K. Chakarova, K. Hadjiivanov, P. Lukinskas, H. Knözinger
Phys. Chem. Chem. Phys. , 5 (2003) 4040 - 4044.
On the Nature of Pd+ Surface Carbonyl and Nitrosyl Complexes Formed on Pd-promoted Tungstated Zirconia Catalysts.

404

K. Hadjiivanov, E, Ivanova, M. Dimitrov, H. Knözinger
J. Mol. Struct., 661/662 (2003) 459 - 463
FTIR spectroscopic study of CO adsorption on Rh-ZSM-5; Detection of Rh+-CO species.

403

S. Kuba, P. Lukinskas, R. Ahmad, F. C. Jentoft, R. K. Grasselli, B. C. Gates, H. Knözinger
J. Catal., 219 (2003) 376 - 388
Reaction pathways in n-pentane conversion catalysed by tungstated zirconia: effects of platinum in the catalyst and hydrogen in the feed.

402

W. Daniell, T. Weingand, H. Knözinger
J. Mol. Catal. A, 204/205 (2003) 519 - 526
Redox properties of Re2O7/Al2O3 as investigated by FTIR spectroscopy of adsorbed CO.

401

P. Lukinskas, S. Kuba, B. Spliethoff, R. K. Grasselli, B. Tesche, H. Knözinger
Top. Catal. 23 (2003) 163 - 173
Role of Promotors on Tungstated Zirconia Catalysts.

400

X. Carrier, J.-F. Lambert, S. Kuba, H. Knözinger, M. Che
J. Mol. Struct., 656 (2003) 231 - 238
Influence of ageing on MoO3 formation in the preparation of alumina-supported Mo catalysts.

399

S. Kannan, D. Kishore, K. Hadjiivanov, H. Knözinger
Langmuir, 19 (2003) 5742 - 5747
FTIR study of low-temperature CO adsorption on MgAl - hydrotalcite and its calcined forms.

398

S. Kuba, M. Che, R. K. Grasselli,  H. Knözinger
J. Phys. Chem. B 107 (2003) 3459 3463
Evidence for the formation of W5+ centers and OH groups upon hydrogen reduction of platinum-promoted tungstated zirconia catalysts.

397

S. Kuba, P. Lukinskas, R. K. Grasselli, B. C. Gates, H. Knözinger
J. Catal.. 216 (2003) 353 - 361
Structure and prperties of tungstated zirconia catalysts for alkene conversion.

396

K. Hadjiivanov, E. Ivanova, H. Knözinger
Microporous Mesoporous Mater. 58 (2003) 225 - 236
FTIR study of low-temperature CO adsorption on Y-zeolite exchanged with Be2+, Mg2+, Ca2+, Sr2+ and Ba2+ cations.

395

R. Craciun, B. Nentwick, K. Hadjiivanov, H. Knözinger
Appl. Catal. A: General 243 (2003) 67 - 79
Structure and redox properties of MnOx/Yttrium-stabilized zirconia (YSZ) catalyst and its use in CO and CH4 oxidation.

394

H. Knözinger, K. Kochloefl
in "UllmannŽs Encyclopedia of Industrial Chemistry" Wiley - VCH, 6. Ed., 2003, P. 315 - 431
Heterogeneous Catalysis and Solid Catalysts.

393

N. E. Kotelnikova, G. Wegener, T. Paakari, R. Serima, E. Windeisen, H. Knözinger, M. Scheithauer, V. N. Demidov, A. V. Shchukarev, A. V. Gribanov
Cellulose Chem. Technol. 36 (2002) 445 - 458
Siver Clusters Intercalation into the Cellulose Matrix. I. Characteristics and Properties of Intercalates by WAXS, EDXA, IR, 13C NMR, XPS and Raman Spectroscopy Methods.

392

H. Knözinger, E. Taglauer
in "Encyclopedia of Catalysis" (I. T. Horvath et al., Eds.), J. Wiley & Sons, 2002, p. 142 - 182
Catalyst Characterization - Heterogeneous.

391

K. Wiesner, H. Knözinger, M. Fleischer, H. Meixner
IEEE Sensors J., 2 (2002) 354 - 359
Working Mechanism of an Ethanol Filter for Selective High-Temperature Methane Gas Sensors.

390

K. Hadjiivanov, P. Lukinskas, H. Knözinger
Catal. Lett. 82 (2002) 73 - 77
Detection of reduced Wn+ sites on WO3-ZrO2 and Pt/WO3-ZrO2 catalysts by infrared spectroscopy of adsorbed NO.

389

K. Hadjiivanov, E. Ivanova, M. Kantschewa, E. Z. Ciftlikli, D. Klissurski, L. Dimitrov, H. Knözinger
Catal. Commun. 3 (2002) 313 - 319
FTIR study of low-temperature CO adsorption on Mn-ZSM-5 and MnY zeolites. Effect of the zeolite matrix on the formation of Mn2+(CO)x geminal species.

388

T. Weingand, S. Kuba, K. Hadjiivanov, H. Knözinger
J. Catal., 209 (2002) 539 - 546.
Nature and Reactivity of the Surface Species Formed after NO Adsorption and NO+O2 Coadsorption on a WO3-ZrO2 Catalyst

387

K. Hadjiivanov, H. Knözinger, A Milusev
Catal. Commun. 3 (2002) 37 - 44.
FTIR study of low - temperature CO adsorption on Cu silicalite-1.

386

W. Daniell, F. Anderle, A. Ponchel, S. Kuba, D. H. Gregory, H. Knözinger
Top. Catal., 20 (2002) 65 - 74.
Characterization and Catalytic Behaviour of VOx-CeO2 Catalysts for the Oxidative Dehydrogenation of Propane.

385

K. Hadjiivanov, H. Knözinger, M. Mihaylov
J. Phys. Chem. B., 106 (2002) 2618 - 2624.
FTIR Study of CO Adsorption on Ni-ZSM-5.

384

R. Craciun, W. Daniell, H. Knözinger
Appl. Catal. A., 230 (2002) 153 - 168.
The Effect of CeO2-Structure on the Activity of Supported Pd Catalysts Used for Methane Steam Reforming.

383

S. Kuba, H. Knözinger
J. Raman Spectrosc., 33 (2002) 325 - 332.
Time-Resolved in situ-Raman Spectroscopy of Working Catalysts  Sulfated and Tungstated Zirconia.

382

P. Concepción, S. Kuba, A. Martinez-Arias, J. M. López Nieto, H. Knözinger
J. Phys. Chem. B, 106 (2002) 2574 - 2582.

FTIR Study of Low-temperature CO Adsorption on Supported Vanadia Catalysts. Nature of the Vanadium Species in Reduced Catalysts.

381

J. Spengler, F. Anderle, E. Bosch, R. K. Grasselli, B. Pillep, P. Behrens, O. B. Lapina, A. A. Shubin, H.-J. Eberle, H. Knözinger
J. Phys. Chem. B, 105 (2001) 10772-10783.
Antimony Oxide-Modified Vanadia-Based Catalysts  Physical Characterization and Catalytic Properties.

380

A. Kohl, C. Linsmeier, E. Taglauer, H. Knözinger
Phys. Chem. Chem. Phys., 3 (2001) 4639-4643.
Influence of support and promoter on the catalytic activity of Rh/VOx/SiO2 model catalysts.

379

W. Daniell, H. Landes, N. E. Fouad, H. Knözinger
J. Mol. Catal: A, 178 (2002) 211 - 218.
Influence of pretreatment atmosphere on the nature of silica-supported Pd generated via decomposition of Pd(acac)2: An FTIR spectroscopic study of adsorbed CO

378

M. Mihaylov, K. Hadjiivanov, H. Knözinger
Catal. Lett., 76 (2001) 59-63.
Formation of Ni(CO)4 during the interaction between CO and silica-supported nickel catalysts: An FTIR spectroscopic study.

377

W. Daniell, N.-Y. Topsøe, H. Knözinger
Langmuir, 17 (2001) 6233-6239.
An FTIR study of the surface acidity of USY zeolites: Comparison of CO, CD3CN and C5H5N probe molecules.

376

D. Mordenti, P. Grotz, H. Knözinger
Catal. Today, 70 (2001) 83-90.
Methylacetylene and Tert-butylacetylene as IR-Probe Molecules for the Characterization of Basicity.

375

K. Hadjiivanov, T. Venkov, H. Knözinger
Catal. Lett. 75 (2001) 55-59.
FTIR spectroscopy study of CO adsorption on Cu/SiO2: formation of new types of copper carbonyls.

374

D. S. Su, V. Roddatis, M. Willinger, G. Weinberg, E. Kitzelmann, R. Schlögl, H. Knözinger
Catal. Lett. 74 (2001) 169-175.
Tribochemical modification of the microstructure of V2O5
.

373

S. Cai, K. M. Neyman, H. Knözinger, N. Rösch
Surface Sci., 479 (2001) 169-182.
Density Functional Model Cluster - Study of Adsorption of Acetylene on Magnesium Oxide.

372

U.-A. Schubert, F. Anderle, J. Spengler, J. Zühlke, H.-J. Eberle, R. K. Grasselli, H. Knözinger
Topics in Catalysis, 15 (2001) 195-200.
Possible effects of site isolation in antimony oxide-modified vanadia/titania catalysts for selective oxidation of o-xylene.

371

K. Hadjiivanov, H. Knözinger, E. Ivanova, L. Dimitrov
Phys.
Chem. Chem. Phys. 3 (2001) 2531-2536.
FTIR study of low-temperature CO and 15N2 adsorption on a CaNaY zeolite: formation of site-specified Ca2+(CO)3 and Ca2+(15N2)3 complexes.

370

K. Hadjiivanov, H. Knözinger
J. Phys. Chem. B, 105 (2001) 4531-4534.
Formation of Ca2+(CO)3 Complexes during Low-temperature CO Adsorption on CaNaY Zeolite.

369

W. Stichert, F. Schüth, S. Kuba, H. Knözinger
J. Catalysis, 198 (2001) 277-285.
Monoclinic and tetragonal high surface area sulfated zirconias in butane isomerization: CO adsorption and catalytic results.

368

G. Mestl, T. Ilkenhaus, D. Spielbauer, M. Dieterle, O. Timpe, J. Krönert, F. Jentoft, H. Knözinger, R. Schlögl
Appl. Catal. (A), 210 (2001) 13-34.
Thermally and Chemically Induced Structural Transformations of Keggin-type Heteropoly Acid Catalysts.

367

K. Hadjiivanov, H. Knözinger
Phys. Chem. Chem. Phys., 3 (2001) 1132-1137.
FTIR study of the CO and NO adsorption and coadsorption on a Cu/SiO2 catalyst: probing the oxidation state of copper.

366

S. V. Filimonova, A. V. Nosov, M. Scheithauer, H. Knözinger
J. Catal., 198 (2001) 89-96.
n-Pentane isomerization over Pt/WOx/ZrO2 catalysts  A 1H and 13C NMR study.

365

S. Kotrel, J. H. Lunsford, H. Knözinger
J. Phys. Chem. B, 105 (2001)3917-3921.
Characterizing Zeolite Acidity by Spectroscopic and Catalytic Means: A Comparison.

364

S. Kuba, B. C. Gates, P. Vijayanand, R. K. Grasselli, H. Knözinger
Chem. Commun. 2001, 321-322.
An active and selective alkane isomerization catalyst: iron- and platinum-promoted tunstated zirconia.

363

S. Labich, E. Taglauer, H. Knözinger
Topics in Catalysis, 14 (2001) 153-161.
Metal-Support Interactions on Rhodium Model Catalysts.

362

M. A. Ulla, R. Spretz, E. Lombardo, W. Daniell, H. Knözinger
Appl.
Catal. B: Environmental, 29 (2001) 217-229.
Catalytic Combustion of Methane on Co/MgO: Characterization of Active Cobalt Sites.

361

S. Eibl, B. C. Gates, H. Knözinger
Langmuir 17 (2001) 107-115.
Structure of WOx/ZrO2 Catalysts Prepared from Hydrous Titanium Oxide Hydroxide: Influence of Preparation Parameters.

360

S. Kuba, P. Concepción Heydorn, R. K. Grasselli, B. C. Gates, M. Che, H. Knözinger
Phys. Chem. Chem. Phys. 3 (2001) 146-154.
Redox properties of tungstated zirconia catalysts: relevance to the activation of n-alkanes.

359

J. M. López-Nieto, P. Concepción, A. Déjoz, F. Melo, H. Knözinger, M. I. Vázquez
Catalysis Today, 61 (2000) 361-367.
Oxidative dehydrogenation of n-butane and 1-butene on undoped and K-doped VOx/Al2O3 catalysts.

358

C. J. Papile, H. Knözinger, B. C. Gates
Langmuir, 16 (2000) 5661-5664.
[Re2(CO)9]2-on Hydroxylated MgO: Formation from [Re2(CO)10] and Evidence of Ion Pairing at the Surface.

357

P. Concepción, S. Kuba, H. Knözinger, B. Solsana, J. M. Lopez Nieto
Stud. Surf. Sci. Catal., 130 (2000) 767-772.
Effect of Potassium on the Structure and Reactivity of Vanadium Species in VOx/Al2O3 Catalysts.

356

S. Kuba, K. Hadjiivanov, H. Knözinger
Stud.
Surf. Sci. Catal., 130 (2000) 1259-1264.
Reactivity of the NOx surface species formed after co-adsorption of NO + O2 on a WO3/ZrO2 catalyst: an FTIR spectroscopic study.

355

W. Daniell, P. Grotz, H. Knözinger, N. C. Lloyd, C. Bailey, P. G. Harison
Stud.
Surf. Sci. Catal., 130 (2000) 2183-2188.
Characterization and Catalytic Activity of Mixed Cu-Cr/CeO2 Catalysts.

354

K. Hadjiivanov, H. Knözinger
Phys. Chem. Chem. Phys., 2 (2000) 2803-2806.
Species formed after NO adsorption and NO + O2 co-adsorption on TiO2: an FTIR spectroscopy study.

353

S. Günther, F. Esch, L. Gregoratti, M. Marsi, M. Kiskinova, U. A. Schubert, P. Grotz, H. Knözinger, E. Taglauer, E. Schütz, A. Schaack, R. Imbihl
X-Ray Microscopy: Proc. 6th Intern. Conf. 2000, p. 219-224.
Spectromicroscopy of Catalytic Relevant Processes with Sub-Micron Resolution.

352

S. Eibl, R. E. Jentoft, B. C. Gates, H. Knözinger
Phys. Chem. Chem. Phys., 2 (2000) 2565-2573.
Conversion of n-pentane and of n-butane catalyzed by platinum-containing WOx/TiO2

351

K. Hadjiivanov, H. Knözinger
J. Catal., 191 (2000) 480-485.
FTIR study of the low-temperature CO adsorption on Cu+-ZSM-5: Evidence of formation of Cu2+(CO)2 species..

350

A. Kohl, S. Labich, E. Taglauer, H. Knözinger
Surface Sci., 454-456 (2000) 974-978.
Agglomeration of supported rhodium on model catalysts

349.

M. Scheithauer, R. E. Jentoft, B. C. Gates, H. Knözinger
J. Catal., 191 (2000) 271-274.
Fe- and Mn-containing Tungstated Zirconia: Characterization by Laser Raman Spectroscopy and Catalysis of n-Pentane Isomerization

348.

S. Kotrel, H. Knözinger, B. C. Gates
Microporous & Mesoporous Mater., 35-36 (2000) 11-20
The Haag-Dessau Mechanism of Protolytic Cracking of Alkanes.

347.

K. Hadjiivanov, P. Concepción, H. Knözinger
Topics in Catalysis, 11/12 (2000) 123-138
Analysis of Oxidation States of Vanadium in Vanadia-Titania Catalysts by the IR Spectra of Adsorbed NO.

346.

S. Günther, L. Gregoratti, M. Kiskinova, E. Taglauer, P. Grotz, U.-A. Schubert, H. Knözinger
J. Phys. Chem. B, 112 (2000) 5440-5446
Photoelectron Spectromicroscopy on the Spreading of MoO3 on Al2O3 Supports.

345..

H. Knözinger
"Catalysis from A to Z", Hrsg. B. Cornils, W.A. Herrman, R. Schlögl, C.-H. Wong, Wiley-VCH, Weinheim, 2000
Contributions to the topics "Clausius-Clapeyron equation", "Dehydration", "Deposition-Precipitation", "Impregnation", "Ion exchange", "Pellets", "Precipitation/co-precipitation", "Solid-solid wetting".

344.

W. Daniell, U.-A. Schubert, R. Glöckler, A. Meyer, K. Noweck, H. Knözinger
Appl. Catal. A, 196 (2000) 247-260
Enhanced Surface Acidity of Mixed Alumina-Silicas.- A Low-Temparature FTIR Study.

343.

N. E. Fouad, P. Thomasson, H. Knözinger
Appl. Catal. A, 196 (2000) 125-133
Surface Reactions of Acetone, Acetylene and Methylbutynol on an Yttrium-Modified Magnesium Oxide Catalyst.

342.

N. E. Fouad, P. Thomasson, H. Knözinger
Appl. Catal. A, 194/195 (2000) 213-225
IR Study of Adsorption and Reaction of Methylbutynol on the Surface of Pure and Modified MgO Catalysts: Probing the catalyst surface basicity.

341.

H. Knözinger
Science, 287 (2000) 1407-1408
Catalysis on oxide surfaces

340.

N. E. Fouad, M. A. Mohamed, M. I. Zaki, H. Knözinger
J. Anal. Appl. Pyrolysis, 53 (2000) 185-193
Thermal and Spectroscopic Studies of the Feasability of Rh Acetate versus Chloride as Precursor for Rh° Metal Catalysts.

339.

J. M. Lopez Nieto, P. Concepción, A. Dejoz, H. Knözinger, F. Melo, M. I. Vazquez
J. Catal., 189 (2000) 147-157
Selective oxidation of n-butane and butenes on vanadium-containing catalysts.

338.

V. V. Terskikh, M. Seidl, H. Knözinger
Colloids and Surfaces, 158 (1999) 249-254
129Xe NMR study of xenon adsorbed on V2O5/TiO2/SiO2 catalysts. 

337.

M. I. Zaki, M. A. Hasan, L. Pasupulety, N. F. Fouad, H. Knözinger
New J. Chem., 23 (1999) 1197-1202
CO and CH4 total oxidation over manganese oxide supported on ZrO2, TiO2, TiO2-Al2O3 and SiO2-Al2O3 catalysts.

336

E. Taglauer, H. Knözinger, S. Günther
Nucl. Instr. Meth. Phys. Res. B, 158 (1999) 638-646
Microprobe applications for the characterization of catalyst systems. 

335. 

K. Hadjiivanov, P. Massiani, H. Knözinger
Phys. Chem. Chem. Phys., 1 (1999) 3831-3838
Low-temperature CO and 15N2 adsorption and co-adsorption on alkali cation exchanged EMT zeolites: an FTIR study.

334

G.N. Vayssilov, M. Staufer, T. Belling, K.M. Neymann, H. Knözinger, N. Rösch
J. Phys. Chem. B., 103 (1999) 7920-7928
Density functional studies of alkali-exchanged zeolites. Cation location at six-rings of different aluminium content.

333. 

B. Pillep, P. Behrens, U.-A. Schubert, J. Spengler, H. Knözinger
J. Phys. Chem. B, 103 (1999) 9595-9603
Mechanical and Thermal Spreading of Antimony Oxides on the TiO2-Surface - Dispersion and Properties of Surface Antimony Oxide Species. 

332. 

K. Hadjiivanov, H: Knözinger, B. Tsyntsarski, L. Dimitrov
Catal. Lett., 62 (1999) 7599-7606
Effect of water on the reduction of NOx with propane on Fe-ZSM-5. An FTIR mechanism study.

331. 

O. B. Lapina, A. A. Shubin, A. V. Nosov, E. Bosch, H. Knözinger
J. Phys. Chem. B, 1030 (1999) 7599-7606
Characterization of on V2O5-TiO2 catalysts prepared by milling by ESR and solid state 1H and 51V NMR. 

330. 

K. Hadjiivanov, B.M. Reddy, H. Knözinger
Appl. Catal. A, 188 (1999) 355-360
FTIR study of the low-temperature adsorption and co-adsorption of 12CO and 13CO on TiO2/SiO2 mixed oxide

329. 

K. Rymsa, H. Hunger, H. Knözinger, J. Weitkamp
Stud. Surf. Sci. Catal., 125 (1999) 197-204
Spectroscopic and Catalytic characterization of basic zeolites and related porous materials. 

328. 

P. Concepción, B. M. Reddy, H. Knözinger
Phys. Chem. Chem. Phys., 1 (1999) 3031-3037
FTIR Study of the Low-temperature CO Adsorption on pure Al2O3-TiO2 and V/Al2O3-TiO2 Catalysts. 

327. 

P. Concepción, K. Hadjiivanov, H. Knözinger 
J. Catal., 184 (1999) 172-179
Low temperature CO adsorption V-containing aluminophosphates: an FTIR study. 

326. 

A. Kohl, E. Taglauer, H. Knözinger 
Phys. Stat. Sol. (a), 173 (1999) 85-91
Morphology and Surface Reactions of Rh/VOx/SiO2 Model Catalysts. 

325. 

M. Sigl, M. C. J. Bradford, H. Knözinger, M. A. Vannice
Topics in Catalysis, 8 (1999) 211-222
CO2 Reforming of Methane over Vanadia-Promoted Rh/SiO2 Catalysts. 

324. 

A. A. Shubin, O. B. Lapina, E. Bosch, J. Spengler, H. Knözinger
J. Phys. Chem B, 103 (1999) 3138-2144
Effect of Milling of V2O5 on the Local Environment of Vanadium as Studied by Solid-State 51V-NMR and Complementary Methods. 

323. 

K. Hadjiivanov, H. Knözinger
Chem. Phys. Lett., 303 (1999) 513-520
FTIR Study of the low-temperature adsorption and co-adsorption of CO and N2 on NaY zeolite: evidence of simultaneous coordination of two molecules to one Na+ site. 

322. 

Hadjiivanov, H. Knözinger 
Catal. Lett., 58 (1999) 21-26.
FTIR Spectroscopic Evidence of Formation of Geminal Dinitrogen Species During the Low-temperature N2 Adsorption on NaY Zeotites. 

321. 

H. Knözinger, G. Mestl
Topics in Catalysis, 8 (1999) 45-55
Laser Raman Spectroscopy- A powerful tool for in situ studies of catalytic materials. 

320. 

S. Huber, H. Knözinger
Appl. Catal. A, 181 (1999) 239-244
Adsorption of CO on Sodium Containing X- and Y-Zeolites and Determination of the Aluminium Distribution. K.

319. 

S. Huber, H. Knözinger
J. Mol. Catal., 141 (1999) 117-127.
Adsorption of CH-Acids on Magnesia. An FTIR Spectroscopic Study. 

318. 

P. Thomasson, O. S. Tyagi, H. Knözinger
Appl. Catal. A, General, 181 (1999) 181-188.
Characterization of the basicity of modified MgO-Catalysts. 

317. 

E. Bosch, S. Huber, J. Weitkamp, H. Knözinger
Phys. Chem. Chem. Phys., 1 (1999) 579-584.
Adsorption of Trichloro- and Trifluoromethane in Y-Zeolites as Studied by Infrared Spectroscopy and Multinuclear Solid State NMR 

316. 

K. Hadjiivanov, H. Knözinger 
J. Phys. Chem. B, 102 (1998) 10936-10940.
Low temperature CO adsorption on Ag/SiO2 and Ag/ZSM-5: an FTIR study. 

315. 

Z. Schay, H. Knözinger, L. Guczi, G. Pál-Borbély
Appl. Catal. B, 18 (1998) 263-271.
On the Mechanism of NO Decomposition on Cu-ZSM-5 Catalysts. 

314. 

M. Scheithauer, T.-K. Cheung, R. E. Jenthoft, R. K. Grasselli, B. C. Gates, H. Knözinger 
J. Catal., 180 (1998) 1-13.
Characterization of WOx/ZrO2 by Vibrational Spectroscopy and n-Pentane Isomerization Catalysis. 

313. 

S. Labich, A. Kohl, E. Taglauer, H. Knözinger
J. Chem. Phys., 109 (1998) 2052-2055.
Silicide Formation by High-Temperature Reaction of Rh with Model SiO2 Films. 

312. 

A. M. Ferrari, K. M. Neyman, S. Huber, H. Knözinger, N. Rösch 
Langmuir, 14 (1998) 5559-5567.
Density Functional Study of Methane Interaction with Alkali and Alkaline-earth Metal Cation Zeolites. 

311. 

M. Scheithauer, H. Knözinger, M. A. Vannice
J. Catal., 178 (1998) 701-705.
Raman Spectra of La2O3 Dispersed on gamma Al2O3

310. 

H. Knözinger
in Challenges for Sulfides in Material Sciences and Catalysis, R. A. van Santen, R. Prins, Th.
Weber (Eds.), Kluwer, Dordrecht, (1998) 189-206.
Characterization of Sulfided Molybdenum-based Catalysts. 

309. 

H. Knözinger, S. Huber
J. Chem. Soc. Faraday Trans., 94 (1998) 2047-2059.
Infrared Spectroscopy of Small and Weakly Interacting Molecular Probes for Acidic and Basic Zeolites

308. 

G. Mestl, H. Knözinger
Langmuir 14 (1998) 3964-3966
Spreading of MoO3 on gamma Al2O3 Induced by Mechanical Activation. 

307. 

A. M. Ferrari, S. Huber, H. Knözinger, K. M. Neyman, N. Rösch
J. Phys. Chem. B, 102 (1998) 4548-4555.
FTIR Spectroscopy and Densitiy funktional Model Cluster Studies of Methane Adsorption on MgO. 

306. 

M. Scheithauer, E. Bosch, U. A. Schubert, H. Knözinger, T.-K. Cheung, F.C. Jentoft, B.C. Gates, B. Tesche, M. Che
J. Catal., 177 (1998) 137-146.
Spectroscopic and Microscopic Characterization of Iron-and/or Manganese-Promoted Sulfated Zirconia. 

305. 

M. Scheithauer, R. K. Grasselli, H. Knözinger
Langmuir, 14 (1998) 3019-3029.
Genesis and Structure of WOx/ZrO2 Solid Acid Catalysts. 

304. 

H. Knözinger
Topics in Catalysis, 6 (1998) 107-110.
Hydrocarbon Deposits Formed during n-butane Isomerization on Sulfated Zirconia. 

303.

W. Vogel, H. Knözinger, B. Carvill, W. M. H. Sachtler, Z. Zhang
J. Phys. Chem., B 102 (1998) 1750-1758.
Mass Diffusion Effect in Large Zeolite Y Aggregates on Pd Cluster Size Distribution: A combined in situ EXAFS/XRD Study in Zeolite Y 

302. 

E. A. Wovchko, J. T. Yates, Jr., M. Scheithauer, H. Knözinger
Langmuir, 14 (1998) 552-555.
Reducing Radiation Damage in Raman Spectroscopy of Powdered Materials. 

301. 

N. E. Foud, H. Knözinger, M. I. Zaki
Z. Phys. Chem., 203 (1998) 131-142.
Chromia on Silica and Alumina Catalysts: CO Oxidation Activity. 

300. 

B. Leyer, H. Schmelz, H. Göbel, H. Knözinger
Thin Solid Films, 310 (1997) 228-233.
Preparation of AlVO4-Films for Sensor Application via a Sol-Gel/Spin Coating Technique. 

299. 

N. E. Kotelnikova, T. Paakari, R. Serimaa, G. Wegener, V. P. Kotelnikov, V. N. Demidov, A. V. Schukarev, E. Windeisen, H. Knözinger, V. I. Kudryashov, A. S. Serebryakov
Macromol. Symp. 114 (1997) 165-171.
Study of Metall Clusters Intercalation into Cellulose by WAXS, Spectroscopic and Microscopic Methods. 

298. 

S. Günther, M. Marsi, A. Kolmakov, M. Kiskinova, N. Noeske, E. Taglauer, U. A. Schubert, G. Mestl, H. Knözinger
J. Phys. Chem.B; 101 (1997) 10004-10011.
Photoelectron Spectromicroscopy Study of the Spreading Behavior of MoO3 on Titania and Alumina Model Supports. 

297. 

F. C. Jentoft, H. Schmelz, H. Knözinger
Appl. Catal., A: General 161 (1997) 167-182.
Preparation of Selective Catalytic Reduction Catalysts via Milling and Thermal Spreading. 

296. 

U. A. Schubert, J. Spengler, R. K. Grasselli, B. Pillep, B. Behrens, H.-J. Eberle, H. Knözinger
Proc. 3rd World Congr. Oxidation Catalysis, San Diego, 1997, Elsevier, Amsterdam, 1997, p. 817-827.
Oxidation Catalysts Prepared by Mechanically and Thermally Induced Spreading of Sb2O3 and V2O5 on TiO2

295. 

M. Scheithauer, R. K. Grasselli, H. Knözinger
PREPRINTS, Amer. Chem. Soc., 42 (1997) 738-740.
Genesis and Structure of WOx/ZrO2 Solid Acid Catalysts. 

294. 

H. Knözinger
Handbook of Heterogeneous Catalysis, G. Ertl, H. Knözinger, J. Weitkamp (Eds.), Wiley-VCH. Vol. 2, p. 707-732. Infrared Spectroscopy for the Characterization of Surface Acidity and Basicity. 

293. 

H. Knözinger
ibid, Vol. 2, p. 676-689. Temperature-Programmed Reduction. 

292. 

G. Mestl, H. Knözinger
ibid, Vol. 2, p. 539-574. Vibrational Spectroscopies. 

291. 

H. Knözinger, E. Taglauer
ibid, Vol. 1, 1997, p. 216-231. Wetting and Spreading. 

290. 

D. Spielbauer, G. A. H. Mekhemer, T. Riemer, M. I. Zaki, H. Knözinger
J. Phys. Chem. B, 101 (1997) 4681-4688.
Structure And Acidic Properties of Phosphate Modified Zirconia. 

289. 

M. Sigl, S. Ernst, J. Weitkamp, H. Knözinger
Catal. Lett., 45 (1997) 27-33.
Acid properties of [Al]-, [Ga]- and [Fe]-HZSM-5 by low temperature FTIR spectroscopy of adsorbed dihydrogen and ethylbenzene disproportionation. 

288. 

T. Beutel, O. S. Alekseev, Yu. A. Ryndin, V. A. Likholobov, H. Knözinger
J. Catal., 169 (1997) 132-142.
FTIR Spectroscopic Study and CO Hydrogenation on V, Nb and Ta Oxide Promoted Rh/SiO2 Catalysts. 

287.

T. Beutel, V. Siborov, B. Tesche, H. Knözinger
J. Catal., 167 (1997) 379-380.
Strong Metal Promotor Oxide Interaction Induced by Calcination in V, Nb and Ta Oxide Promoted Rh/SiO2 Catalysts. 

286. 

S. E. Deutsch, G. Mestl, H. Knözinger, B. C. Gates
J. Phys. Chem., 101 (1997) 1374-1384.
MgO-Supported Tetrairidium Clusters: Evidence of the Metal-Support Interface Structure from X-ray Absorption Spectroscopy. 

285. 

B. Pillep, A. M. Schneider, U. A. Schubert, J. Spengler,H. Knözinger, P. Behrens
HASYLAB Jahresbericht 1996, 328-329.
Sb L-Edge XANES Spectroscopic Investigation of the Structure of Sb-Ti oxide Catalyst-Precursors Prepared by Mechanical Activation. 

284. 

T. Hartmann, H. Knözinger
Z. Phys. Chem., 197 (1996) 113-124.
Structure and Reactivity of VOx/Rh(111) Model Catalysts. 

283. 

H. Knözinger
Catal. Today, 32 (1996) 71-80.
In situ Raman spectroscopy. - A powerful tool for studies in selective catalytic oxidation. 

282. 

Ch. Linsmeier, H. Knözinger, E. Taglauer
Nucl. Instr. Meth. B., 118 (1996) 553.
Depth Profile Analysis of Strong Metal-Support Interactions on Rh/TiO2 Model Catalysts. 

281. 

D. Spielbauer, G.A.H. Mekheimer, M.I. Zaki, H. Knözinger
Catal. Lett., 40 (1996) 71-79.
Acidity of sulfated zirconia as studied by FTIR spectroscopy of adsorbed CO and NH3 as probe molecules. 

280. 

A. Burrows, C.J. Kiely, R.W. Joyner, H. Knözinger, F.C. Lange
Catal. Lett., 39 (1996) 219-231.
An HREM study of the WO3 / TiO2 monolayer catalyst system. Proposals for the overlayer structure. 

279. 

G. Mestl, N.F.D. Verbruggen, E. Bosch, H. Knözinger
Langmuir, 12 (1996) 2961-2968.
Mechanically Activated MoO3. 5. Redox Behavior. 

278. 

J. Weitkamp, S. Ernst, M. Hunger, T. Röger, S. Huber, U.A. Schubert, P. Thomasson, H. Knözinger
Proc. 11th Intern. Congr. Catal., Eds. J.W. Hightower, W.N. Delgass, E. Iglesia, A.T. Bell, Elsevier, Amsterdam, 1996, pp.731-740.
Solid state ion exchange of alkali metal cations into zeolite Y: Physicochemical characterization and catalytic tests. 

277. 

F.C. Lange, H. Schmelz, H. Knözinger
Appl. Catal. B, Environmental, 8 (1996) 245-265.
Infrared-Spectroscopic investigations of selective catalytic reduction catalysts poisoned with arsenic oxide. 

276. 

T. Riemer, H. Knözinger
J. Phys. Chem., 100 (1996) 6739-6742.
31P Solid State NMR and ESR Investigation of Trimethylphosphane Adsorption on Zirconia and Sulfated Zirconia. 

275. 

G. Mestl, N.F.D. Verbruggen, F.C. Lange, B. Tesche, H. Knözinger
Langmuir, 12 (1996) 1817-1829.
Mechanically Activated MoO3. 4. In situ Characterization of Physical Mixtures with Al2O3

274. 

D. Spielbauer, G.A.H. Mekheimer, T. Riemer, H. Knözinger
Proc. DGMK-Conference "Catalysis on Solid Acids and Bases", March 14-15, 1996, Berlin, J. Weitkamp und B. Lücke, Eds., DGMK, Hamburg, 1996, pp.79-86.
Characterization and Catalytic Properties of Sulfated Zirconia. 

273. 

D. Spielbauer, G.A.H. Mekhemer, E. Bosch, H. Knözinger
Catal. Lett., 36 (1996) 59-68.
n-Butane Isomerization on Sulfated Zirconia - Deactivation and Regeneration as studied by Raman-, UV-VIS diffuse Reflectance and ESR-Spectroscopy. 

272. 

E. Taglauer, H. Knözinger
Phys. stat. solidi, 192 (1995) 465-475.
Characterization of Supported Catalyst Systems with Surface Spectroscopies. 

271. 

G. Mestl, T.K.K. Srinivasan, H. Knözinger
Langmuir, 11 (1995) 3795-3804.
Mechanically Activated MoO
3. III. Characterization by Vibrational Spectroscopy. 

270. 

V. M. Mastikhin, V.V. Terskikh, O.B. Lapina, S.V. Filimonova, M. Seidl, H. Knözinger
J. Catal., 156 (1995) 1-10.
Characterization of (V
2O5-WO3) on TiOx/Al2O3 Catalysts by 1H-,15N-, and 51V-Solid State NMR Spectroscopy. 

269. 

V. M. Mastikhin, V.V. Terskikh, O.B. Lapina, S.V. Filimonova, M. Seidl, H. Knözinger
Solid State Nucl. Magn. Res., 4 (1995) 369-379.
1H, 51V and 15N nuclear magnetic resonance studies of 
structure and properties of vanadia supported TiO
x /SiO2

268. 

S. Huber, H. Knözinger
Chem. Phys. Lett., 244 (1995) 111-116.
FTIR spectroscopic studies of methane adsorption on sodium and cesium containing Y-zeolites. 

267. 

G. Mestl, N.F.D. Verbruggen, H. Knözinger
Langmuir, 11 (1995) 3035-3041.
Mechanically Activated MoO3. II. Characterization of Defect Structures. 

266. 

G. Mestl, B. Herzog, R. Schlögl, H. Knözinger
Langmuir, 11 (1995) 3027-3034.
Mechanically Activated MoO3. I. Particle Size, Crystallinity and Morphology. 

265. 

P. Strodel, K.M. Neyman, H. Knözinger, N. Rösch
Chem. Phys. Letters, 240 (1995) 547-552.
Acidic Properties of [Al], [Ga] and [Fe] Isomorphously Substituted Zeolites. Density Functional Model Cluster Study of the Complexes with a Probe CO Molecule. 

264. 

P. Mottner, T. Butz, A. Lerf, G. Ledezma, H. Knözinger 
J. Chem. Phys., 99 (1995) 8260-8269.
99Mo(ß-)99>/SUP>Tc-Spectroscopy of MoS
2, lithiated MoS2, Co0.5MoS2 and MoS2 Surface Species. 

263. 

K. M. Neyman, P. Strodel, S.Ph. Ruzankin, N. Schlensog, H. Knözinger, N. Rösch
Catal. Lett., 31 (1995) 273-285.
N
2 and CO Molecules as Probes of Zeolite Acidity: An Infrared Spectroscopy and Density Functional Investigation. 

262. 

J. Miciukiewicz, T. Mang, H. Knözinger
Appl. Catal. A., 122 (1995) 151-159.
Raman Spectroscopy Characterization of Molybdena Supported on Titania-Zirconia Mixed Oxide. 

261. 

G. Mestl, P. Ruiz, B. Delmon, H. Knözinger
J. Phys. Chem., 98 (1994), 11283-11292.
In Situ Raman Spectroscopy Characterization of the 18O-Exchange in Physical Mixtures of Antimony Oxides and Molybdenum Oxide. 

260. 

G. Mestl, P. Ruiz, B. Delmon, H. Knözinger
J. Phys. Chem., 98 (1994), 11276-11282.
Sb
2O3/Sb2O4 in Reducing/Oxidizing Environments: An In Situ Raman Spectroscopy Study. 

259. 

G. Mestl, P. Ruiz, B. Delmon, H. Knözinger
J. Phys. Chem. 98 (1994), 11269-11275.
Oxygen Exchange Properties of MoO
3: An In Situ Raman Spectroscopy Study. 

258. 

T. Beutel, B.L. Moroz, H. Knözinger
Rec. Trav. Chim. Pays-Bas, 113 (1994), 448-453.
Adsorption of Diacetyl on Rh/SiO2 Catalysts
- An FTIR Study. 

257. 

N.F.D. Verbruggen, H. Knözinger
Langmuir, 10 (1994), 3148-3155.
Reducibility and Hydrodesulfurization Activity of K-doped MoOx/Al2O3 and MoOx/SiO2 Catalysts. 

256. 

N.F.D. Verbruggen, G. Mestl, L.M.J. von Hippel, B. Lengeler, H. Knözinger
Langmuir, 10 (1994), 3073-3080.
Structure of K-doped Molybdena-on-Alumina Catalysts as Studied by X-ray Absorption and Raman Spectroscopy. 

255. 

N.F.D. Verbruggen, L.M.J. von Hippel, G. Mestl, B. Lengeler, H. Knözinger
Langmuir, 10 (1994), 3063-3072.
Structure of K-doped Molybdena-on-Silica Catalysts as Studied by X-ray Absorption and Raman Spectroscopy. 

254. 

B. Tesche, T. Beutel, H. Knözinger
J. Catal., 149 (1994), 100-116.
Structure and Morphology of Vanadia-Promoted Rh/SiO2: A Transmission Electron Microscopy Study. 

253. 

O.S. Alekseev, T. Beutel, E.A. Paukshits, Yu. A. Ryndin, V.A. Likholobov, H. Knözinger
J. Molec. Catal., 99 (1994) 217-233.
FTIR Studies of CO Chemisorption and Reactivity on Rh/SiO
2-Catalysts Promoted by Niobium Oxide. 

252. 

T. Riemer, D. Spielbauer, M. Hunger, G.A.H. Mekheimer, H. Knözinger
J. Chem. Soc. Chem. Commun., (1994) 1181-1182.
Superacid Properties of Sulfated Zirconia as Measured by Raman Spectroscopy and 1H-MAS-NMR. 

251. 

T. Beutel, H. Knözinger, H. Trevino, Z.C. Zhang, W.M.H. Sachtler, C. Dossi, R. Psaro, R. Ugo
J. Chem. Soc. Faraday Trans., 90 (1994) 1335-1344.
Manganese-Promoted Rhodium/NaY Zeolite Catalysts 
- An Infrared Study. 

250. 

I. Mirsojew, St. Ernst, J. Weitkamp, H. Knözinger
Catal. Lett., 24 (1994) 235-248.
Characterization of Acid Properties of [Al]- and [Ga]-HZSM-5 Zeolites by Low Temperature Fourier Transform Infrared Spectroscopy of Adsorbed Carbon Monoxide. 

249. 

N.E. Fouad, H. Knözinger, M.I. Zaki 
Z. Phys. Chem., 186 (1994) 231-244.
Chromia on Silica and Alumina Catalysts: Temperature-Programmed Reduction and Structure of Surface Chromates. 

248. 

A. Burrows, C. J. Kiely, R. W. Joyner, H. Knözinger, F. Lange
Mater. Res. Soc. Symp. Proc. 344 (1993) 33-38.
Microstructural Studies of the WO3/TiO2 Monolayer Catalyst System Using High Resolution Electron Microscopy. 

247. 

A. Burrows, R. W. Devenish, R. W. Joyner, J. C. Kiely, H. Knözinger, F. Lange
Inst. Phys. Conf. Ser. No. 138: Section 10, 1993, 481-484.
A structural study of the WO3/TiO2 (anatase) monolayer catalyst using high resolution electron microscopy. 

246. J.H. Lunsford, X. Yang, K. Haller, J. Laane, G. Mestl, H. Knözinger
J. Phys. Chem., 97 (1993) 13810-13813.
In situ Raman Spectroscopy of Peroxide Ions on Ba/MgO Catalysts.   
   


 

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